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How to become a CompTIA certified Instructor ?

There is no such distinction as a CompTIA certified Instructor.

It's strongly recommended that you pass the certification exam for the CompTIA course you will be teaching, but there is no official designation of CompTIA-certified instructor. CompTIA had a Certified Technical Trainer (CTT+) certification but retired it a few years ago.
 
@Gregory Childers thanks for your response. Kindly guide from where or how I can have access to official training materials like PPTs for the new courses.

thanks in advance.
Karthik: To get a hold of official curriculum from CompTIA, you'll need to connect to your CompTIA Business Development Manager if you/your organization is a Partner with CompTIA.